With compression ratios, which to my way of thinking should be thought of as geometric, there are other, interactive influences to consider.
Super unleaded will tolerate higher compression. The ignition advance will be instrumental upon the avoidance of pre-ignition. The plug grade is important. The piston itself & it's underside's ability to transfer heat, as well as it's mass. The best pistons are most likely those with a waffled underside. The number & configuration of transfer ports impacts upon the cooling of the crown. Then, of course, there is the exhaust. Any decent exhaust, which will be an effective expansion chamber, will cause the higher compression engines to start incurring pumping losses & the loss of any chance of over-rev which is a good thing to have with the restrictions of a four speed box when going down hill

An exhaust in conjunction with a 'kitted' engine needs a bleed of an inch bore for a 200, & that formula should be applied to the varying capacities IMO for an engine to run cooler.
However, the ability of the cylinder head to do it's job of shedding heat relies upon the tightest, safe squish possible & that should be contoured to suit the piston crown, not just a straight cut that is 'near enough' as is so often the case. With great care, the profile of head to crown can be matched by attaching some fine abrasive paper to the crown (a ring, or 'polo' shape works well) & lapping the two together in the head to cylinder assembly. Obviously, the head to cylinder should be spigotted or dowelled for positional accuracy.
What shouldn't be overlooked is that with the generic overall size of an OEM type head is that as a consequence, a 125 can run considerably higher compression than a 225 as it will have greater mass.
Ultimately, without the luxury of a dyno to hand, which some of us can ill afford, a keen ear will detect pinking. A keen eye will read the plug.
My rule of thumb is to aim for 9.5:1 maximum for the large block engines with fixed ignition, decreasing with capacity rise, though an alloy barrel helps with the conduction of heat. About 10:1 maximum for a 175 Indian alloy barrel, though the time involved in making them run well is colossal......